Bidentate selenium-based chalcogen bond catalyzed cationic polymerization of p-methoxystyrene

文献情報

出版日 2024-01-02

DOI 10.1039/D3CC05516G

インパクトファクター 6.222

著者

Hao Chen, Hongjun Fu, Ji Xian, Xiaobo Pan, Jincai Wu

原文を見る

要旨

The application of selenium-based non-covalent bond catalysis in living cationic polymerization has rarely been reported. In this work, the cationic polymerization of p-methoxystyrene (pMOS) was performed using a bidentate selenium bond catalyst – a new water-tolerant Lewis acid catalyst. A polymer with controllable molecular weight and narrow molecular weight distribution can be obtained at room temperature, with a maximum molecular weight of 23.3 kDa. This selenium bond compound can also catalyze the controllable cationic polymerization of p-methoxy styrene under environmental conditions. By changing the monomer feeding ratio, a secondary feeding experiment and DFT analysis, it is shown that the selenium bond catalyst can induce polymer chain growth by reversibly activating dormant covalent bonds (C–OH).

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Bidentate selenium-based chalcogen bond catalyzed cationic polymerization of p-methoxystyrene

文献情報

おすすめジャーナル

関連文献

2H and 19F solid-state NMR studies of the ionic liquid [C2Py][BTA]-d10 confined in mesoporous silica materials

Population transfer for signal enhancement in pulsed EPR experiments on half integer high spin systems

Proton mobility through a second order phase transition: theoretical and experimental study of LaNbO4

First-principles simulations of hydrogen peroxide formation catalyzed by small neutral gold clusters

Enantioselective binding of structural epoxide isomers by a chiral vanadyl salen complex: a pulsed EPR, cw-ENDOR and DFT investigation

In situ infrared (FTIR) study of the mechanism of the borohydride oxidation reaction

Inhibition of efflorescence in mixed organic–inorganic particles at temperatures less than 250 K

Spin-dynamics of the spin-correlated radical pair in photosystem I. Pulsed time-resolved EPR at high magnetic field

Magnetic quantum tunneling: key insights from multi-dimensional high-field EPR

A kinetic study of the decomposition of the cubic perovskite-type oxide BaxSr1−xCo0.8Fe0.2O3−δ (BSCF) (x = 0.1 and 0.5)

こちらもおすすめ

2-氟-4-イオドベンzo酸エチルエステルを取り扱う際の実験室安全事項は何ですか？

血根碱の主な用途は何ですか？

Methyl 3-methoxythiophene-2-carboxylateの主な用途は何ですか？

丹磺酰-L-亮氨酸はどのように保存すればよいですか？

5-(苄氧基)ピラミジン-4-アミンの代替品はありますか？

8-ヒドロキシノルデコペントアセートの物理化学的性質は何ですか？

tert-ブチル(エス)-1-ヒドロキシペンタ-4-エン-2-イルカルバamateの主な用途は何ですか？

ブコール-L-2-フローヨルブリンについて適切な法規ガイドラインは何ですか？

6-ブロモ-N-環丙基-2-ピリジニニメタンの市場動向や研究トレンドはどうですか

RS-AMPÀはどのように保存すればよいですか？

掲載誌

Chemical Communications

おすすめ化合物

(2E)-3-(2,6-Difluorophenyl)acrylic acid

2-Hydroxy-4-[({[(4-methylphenyl)sulfonyl]oxy}acetyl)amino]benzoic acid

1-Methyl-2-propylbenzene

Fluifort

1-(Hexyloxy)hexane

おすすめサプライヤー