Expedient synthesis of a symmetric cycloheptyne-Co2(CO)6 complex for orthogonal Huisgen cycloadditions

文献情報

出版日 2019-02-28

DOI 10.1039/C9QO00086K

インパクトファクター 5.281

著者

Morgan Cormier, Eric Fouquet, Philippe Hermange

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要旨

A short procedure to prepare a cycloheptyne di-cobalt-carbonyl complex functionalised by a terminal alkyne is reported. This symmetric complex can react selectively in Strain Promoted Alkyne Azide Cycloaddition (SPAAC) or Copper Catalysed Alkyne Azide Cycloaddition (CuAAC) depending on the conditions, providing a new and practical tool for orthogonal conjugation reactions with azido reagents.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Expedient synthesis of a symmetric cycloheptyne-Co2(CO)6 complex for orthogonal Huisgen cycloadditions

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