Characterization of binary solvent mixtures: the water–acetonitrile mixture

文献情報

出版日 2003-01-06

DOI 10.1039/B210405A

インパクトファクター 3.876

著者

Francisco García-Blanco

原文を見る

要旨

Binary mixtures of water and acetonitrile (W/AN) were characterized in the light of the pure solvent scales, using suitable probe/homomorph couples. Various thermodynamic (vapour pressure, softness parameter, excess molar Gibbs energy and enthalpy of mixing) properties, surface tension, viscosity, and spectroscopic (IR, Raman and NMR) properties of the mixtures, and the distribution of molecular structures (viz. free CH3CN and CH3CN–H2O complexes) are described in terms of their polarity, acidity and basicity, and the descriptions examined in relation to a potential physical significance.

掲載誌

Organic & Biomolecular Chemistry

CiteScore: 3.4

自己引用率: 10.3%

年間論文数: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Characterization of binary solvent mixtures: the water–acetonitrile mixture

文献情報

おすすめジャーナル

関連文献

Designing ionic liquids for absorptive cooling

Fluoro-functionalized polymeric ionic liquids: highly efficient catalysts for CO2 cycloaddition to cyclic carbonates under mild conditions

Imidazolium ionic liquid-tagged palladium complex: an efficient catalyst for the Heck and Suzuki reactions in aqueous media

Mesoporous carbon–silica solid acid catalysts for producing useful bio-products within the sugar-platform of biorefineries

An alternative method for the production of second-generation biofuels

Hydrothermal saline promoted grafting: a route to sulfonic acid SBA-15 silica with ultra-high acid site loading for biodiesel synthesis

Rational investigations in the ring opening of cyclic carbonates by amines

High-yield production of levulinic acid from cellulose and its upgrading to γ-valerolactone

Coupling metal halides with a co-solvent to produce furfural and 5-HMF at high yields directly from lignocellulosic biomass as an integrated biofuels strategy

Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents

こちらもおすすめ

6-苄基-6,7-二氢-5H-吡咯并3,4-b吡啶とは何ですか？

半硫酸奎宁单水水合物はどのように保存すればよいですか？

D-核糖-5-リン酸二ナトリウムとは何ですか？

異丙基肼はどの業界で使用されていますか？

3-乙酰基-4-羟基喹啉-2(1H)-酮はどのように合成されますか？

Bobcat339はどのように保存すればよいですか？

5-溴-4-甲基-1H-吲唑とは何ですか？

3-(4メトキシフェニル)オキテナン-3カーボイル酸の代替品はありますか？

3-イリドオキシピロロ[2,3-b]ピリジン-5-カルボキシlic酸は安全ですか？

3-氟-4- iodobenolを取り扱う際の実験室安全事項は何ですか？

掲載誌

Organic & Biomolecular Chemistry

おすすめ化合物

(3-Aminotetrahydro-3-furanyl)methanol

4,6-O-Ethylidene-D-glucopyranose

trans-2-{[(Tert-butoxy)carbonyl]amino}cyclobutane-1-carboxylic acid

BIS(I-PROPYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE

4-Bromo-2-(methylsulfonyl)pyridine

おすすめサプライヤー