C–H bond chlorination using nickel(ii) complexes of tetradentate amido-quinoline ligands

文献情報

出版日 2022-02-28

DOI 10.1039/D2CC00639A

インパクトファクター 6.222

著者

Sanjay Adhikari, Aniruddha Sarkar, Basab Bijayi Dhar

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要旨

Ni(II)-tetradentate amido-quinoline complexes effectively catalysed C–H chlorination of a series of hydrocarbons in the presence of NaOCl and acetic acid. The bond dissociation energy of the C(sp3)–H bond of the substrates varies from 99.3 kcal mol−1 (cyclohexane) to 87 kcal mol−1 (ethyl benzene). Exclusively chlorinated products (TON: 220 for cyclohexane) were obtained without any hydroxylated products, thus mimicking the activity of the halogenase enzyme.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

C–H bond chlorination using nickel(ii) complexes of tetradentate amido-quinoline ligands

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