Cross-linking approaches for block copolymer nano-assemblies via RAFT-mediated polymerization-induced self-assembly

文献情報

出版日 2020-06-09

DOI 10.1039/D0PY00627K

インパクトファクター 5.582

著者

Shenzhen Li, Guang Han

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要旨

Covalent cross-linking is a simple and robust way to stabilize block copolymer nano-assemblies prepared by reversible addition–fragmentation chain transfer polymerization mediated polymerization-induced self-assembly (RAFT-mediated PISA). To date, various multi-functional compounds with different reactive moieties have been explored for cross-linking of block copolymer nano-assemblies, and these cross-linking approaches can be classified into in situ cross-linking and post-polymerization cross-linking. Owing to the efficient and diverse operations of these cross-linking approaches, various cross-linked block copolymer nano-assemblies with complex morphologies have been constructed, exhibiting superior structural stability against solvent switching or external stimulus. The aim of this review is to summarize the current cross-linking approaches to stabilize block copolymer nano-assemblies obtained via RAFT-mediated PISA process as well as their potential applications.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Cross-linking approaches for block copolymer nano-assemblies via RAFT-mediated polymerization-induced self-assembly

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