Can all bulk-phase reactions be accelerated in microdroplets?

文献情報

出版日 2017-03-14

DOI 10.1039/C6AN02225A

インパクトファクター 4.616

著者

Shibdas Banerjee, Elumalai Gnanamani, Xin Yan, Richard N. Zare

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要旨

Recent studies have shown that microdroplet reactions are markedly accelerated compared to the corresponding bulk-phase reactions. This raises the question whether all reactions can be sped up by this means. We present a counter example, and we show that the reaction mechanism in microdroplets can differ sharply from that in bulk, especially because of the distinct microdroplet surface environment. This analysis helps to guide us how to choose and control reactions in microdroplets and provides a possible perspective on utilizing microdroplet chemistry to scale up synthesis.

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Analyst

CiteScore: 7.8

自己引用率: 5.6%

年間論文数: 653

Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.

Can all bulk-phase reactions be accelerated in microdroplets?

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