An efficient approach to generate aryl carbenes: gold-catalyzed sequential activation of 1,6-diynes

文献情報

出版日 2016-12-21

DOI 10.1039/C6QO00769D

インパクトファクター 5.281

著者

Tongxiang Cao, Kai Chen

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要旨

An efficient approach to generate aryl gold carbenes has been developed. The reaction was proposed to proceed through an intramolecular sequential activation of a 1,6-diyne and aromatization to produce the desired aryl carbene, which was featured with a safe and practical process, mild reaction conditions and high atom efficiency.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

An efficient approach to generate aryl carbenes: gold-catalyzed sequential activation of 1,6-diynes

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