A mechanistic rationalization of unusual kinetic behavior in proline-mediated C–O and C–N bond-forming reactions

文献情報

出版日 2006-08-31

DOI 10.1039/B609926B

インパクトファクター 6.222

著者

Suju P. Mathew, Martin Klussmann, Hiroshi Iwamura, David H. Wells, Jr., Alan Armstrong

原文を見る

要旨

Kinetic evidence supports the role of the reaction product in the catalytic cycle of proline-mediated α-aminoxylation and α-amination reactions, providing both design principles as well as a model for the evolution of efficiency in catalysis.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

A mechanistic rationalization of unusual kinetic behavior in proline-mediated C–O and C–N bond-forming reactions

文献情報

おすすめジャーナル

関連文献

A supramolecular polymer gel with dual-responsiveness constructed by crown ether based molecular recognition

Preparation of a highly reactive polymer click reagent, PEG nitrile N-oxide, and its application in block and star polymer synthesis

Functionalization of aliphatic polyesters by nitroxide radical coupling

Front cover

Dynamic supramolecular self-assembly: hydrogen bonding-induced contraction and extension of functional polymers

Hyperbranched PEG-based multi-NHS polymer and bioconjugation with BSA

New violet to yellow light sensitive diketo pyrrolo–pyrrole photoinitiators: high performance systems with unusual bleaching properties and solubility in water

Poly(fluoroacrylate)s with tunable surface hydrophobicity via radical copolymerization of 2,2,2-trifluoroethyl α-fluoroacrylate and 2-(trifluoromethyl)acrylic acid

Boron difluoride formazanate copolymers with 9,9-di-n-hexylfluorene prepared by copper-catalyzed alkyne–azide cycloaddition chemistry

Ultra-sensitive detection of explosives in solution and film as well as the development of thicker film effectiveness by tetraphenylethene moiety in AIE active fluorescent conjugated polymer

こちらもおすすめ

除水剤ALT-201は安全ですか？

「邻羟基阿托伐他汀内酯标准品」に適用される法規ガイドelinesは何ですか？

メチル（3R）-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩の主な用途は何ですか？

トランス-4-メチルピロリジン-3-オール塩酸塩はどのように合成されますか？

硫雜環丁烷-1,1-二氧化物は安全ですか？

ブラエリリンの主な用途は何ですか？

9-ヒドロキシエリプチシネ塩酸塩はどのように合成されますか？

5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮の物理化学的性質は何ですか？

1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪はどのように保存すればよいですか？

2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンの主な用途は何ですか？

掲載誌

Chemical Communications

おすすめ化合物

N,4-Dimethylaniline hydrochloride (1:1)

ent-Lurasidone Hydrochloride

2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride

1-(1,3-Thiazol-4-yl)ethanamine

(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid

おすすめサプライヤー