Preparation of a highly reactive polymer click reagent, PEG nitrile N-oxide, and its application in block and star polymer synthesis

文献情報

出版日 2017-02-06

DOI 10.1039/C7PY00100B

インパクトファクター 5.582

著者

Toyokazu Tsutsuba

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要旨

The polymer nitrile N-oxide containing poly(ethylene glycol) (PEG) skeleton PEG-CNO was synthesized via a stepwise reaction. The catalyst-free click reaction of PEG-CNO with terminal CC bond-tethering compounds afforded the corresponding diblock and multi-arm star polymers in high yields. The click reactions under solvent-free conditions resulted in significant rate acceleration and high yields of the polymers.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Preparation of a highly reactive polymer click reagent, PEG nitrile N-oxide, and its application in block and star polymer synthesis

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Polymer Chemistry

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