Odyssey and oddity: Photo- and collision processes you would not expect
文献情報
A long-standing investigation of one intriguing collision process, Penning detachment, involved a series of theoretical studies and then experiments intended to exhibit the phenomenon. After some exploratory studies, the experiments, to our surprise, produced clear, unambiguous results that were due to an altogether different process. Identifying and pursuing that process required further theory as well as more experiments. The outcome, reviewed here, has been (a) predicted cross sections for Penning detachment of electrons from negative atomic and cluster ions; (b) predictions of cross sections for resonant two-photon and above-threshold three-photon ionization, (c) measurements of cross sections for superelastic collisions of slow electrons with excited atoms, and, still in progress, (d) theoretical values for cross sections of such superelastic collisions. The experimental method offers a new way to carry out studies of collisions of slow electrons with very high energy resolution.
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掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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