Isothermal vapor–liquid equilibria of binary systems of carbon dioxide and 1-butyne, compared to other binary CO2 + C4Hn systems in terms of global parameters
文献情報
M. Bardas, N. Dahmen, T. Kraska, K.-D. Wagner, L. Yelash
Isothermal vapor–liquid equilibria have been measured for binary systems carbon dioxide and 1-butyne at 303, 313, and 333 K. In advance, the accuracy of the experimental method was checked with the binary system carbon dioxide + n-butane in comparison to literature data. The measurements were performed using an analytical method with a recirculation view cell apparatus. The experimental data were correlated with the Peng–Robinson equation of state. The interaction parameters kij of the binary systems of carbon dioxide and n-butane, isobutane, 1-butene, and 1,3-butadiene were calculated and compared. The kij-values turned out to decrease with increasing degree of unsaturation of the hydrocarbons. The binary mixtures of carbon dioxide with C4-hydrocarbons were located in a global phase diagram calculated for the Peng–Robinson equation of state for the first time here. The analysis of the global phase diagram shows that the unsaturation of the C4 molecules has a quantitative effect on the phase behaviour in contrast, for example, to the chain length effect.
おすすめジャーナル

Current Opinion in Solid State & Materials Science

Journal of Saudi Chemical Society

Russian Chemical Bulletin

Saudi Pharmaceutical Journal

Drug Discovery Today

Russian Journal of Coordination Chemistry

Russian Journal of Bioorganic Chemistry

Nature Medicine

Organic Process Research & Development

New Journal of Chemistry
関連文献
A Rh-catalyzed three-component reaction for the diastereoselective synthesis of pyrazolone derivatives with contiguous quaternary stereocenters
Chaoqun Ao, Jingjing Huang, Xinfang Xu, Shikun Jia, Zhenghui Kang, Wenhao Hu
DOI: 10.1039/D0OB00482K
p-TsOH-mediated synthesis of substituted 2,4-diaryl-3-sulfonylquinolines from functionalized 2-aminobenzophenones and aromatic β-ketosulfones under microwave irradiation
Chieh-Kai Chan, Chien-Yu Lai, Wei-Chih Lo, Yu-Ting Cheng, Cheng-Chung Wang
DOI: 10.1039/C9OB02445J
Synthesis of monofluorooxazoles with quaternary C–F centers through photoredox-catalyzed radical addition of methylene-2-oxazolines
Chuan-Hua Qu, Jin-Hong Chen, Zhi-Gang Xu, Cheng-He Zhou, Zhong-Zhu Chen
DOI: 10.1039/D0OB00267D
Radiopharmacological evaluation of a caspase-3 responsive probe with optimized pharmacokinetics for PET imaging of tumor apoptosis
Ke Li, Siqin Ye, Qingzhu Liu, Ying Peng, Gaochao Lv
DOI: 10.1039/D0OB00690D
Highly selective staining and quantification of intracellular lipid droplets with a compact push–pull fluorophore based on benzothiadiazole
S. Israel Suarez, Caroline C. Warner, Heather Brown-Harding, Andrea M. Thooft, Brett VanVeller, John C. Lukesh, III
DOI: 10.1039/C9OB02486G
Rh-Catalyzed C–H activation/intramolecular condensation for the construction of benzo[f]pyrazolo[1,5-a][1,3]diazepines
Yi Ning, Xinwei He, Youpeng Zuo, Jian Wang, Qiang Tang, Mengqing Xie, Ruxue Li, Yongjia Shang
DOI: 10.1039/D0OB00382D
1-(2H-Azirine-2-carbonyl)benzotriazoles: building blocks for the synthesis of pyrrole-containing heterocycles‡
Ekaterina E. Galenko, Firuza M. Shakirova, Vladimir A. Bodunov, Mikhail S. Novikov, Alexander F. Khlebnikov
DOI: 10.1039/D0OB00206B
Blue emissive dimethylmethylene-bridged triphenylamine derivatives appending cross-linkable groups
Kangyu Zhou, Hongfei Pan, Yongjie Zhang, Houchen Wang, Xiaofei Dong, Xiangkui Ren, Xianggao Li, Shirong Wang, Zhijian Chen
DOI: 10.1039/D0OB00622J
A highly efficient method for the construction of cyclopropane-containing dihydroindole derivatives from indolemethylenecyclopropanes with DIAD and DEAD
Mintao Chen, Wenqing Zang, Yin Wei, Min Shi
DOI: 10.1039/C9OB02520K
Asymmetric total syntheses of naturally occurring α,β-enone-containing RALs, L-783290 and L-783277 through intramolecular base-mediated macrolactonization reaction
Joy Chakraborty, Samik Nanda
DOI: 10.1039/D0OB00237B
こちらもおすすめ
アエポキシアビレーターONE酢酸エステルを含む廃棄物はどのように処理すべきですか?
アエポキシアビレーターONE酢酸エステルを含む廃棄物は、焼却や専門廃棄処理が一般的です。具体的には、廃棄物は密閉容器に収集し、適切な温度と湿度の下で保存します。...
4-ヒドロキシ但線を取り扱う際の実験室安全事項は何ですか?
取り扱いには化学製品安全管理データシート(SDS)を参照してください。温度10℃以下で保存し、密閉容器に保管してください。漏れ時にはドラフトチャンバーを使用し、...
4-(3-環戊基尿素)フェノールボロネートはどの業界で使用されていますか?
4-(3-環戊基尿素)フェノールボロネートは主に医薬品産業で使用されています。この化合物は抗炎症薬や抗うつ薬の候補物質として研究されています。また、ポリマー産業...
N~1~-[3-氯-5-(三氟甲基)-2-吡啶]-1,2-乙二胺の市場動向や研究トレンドはどうですか?
市場では、安全性と効果性を基にした化学物質の需要が高まっています。研究分野では、環境に優しい代替品の開発が進んでおり、その結果、この化合物の市場需要は減少傾向に...
6-硝基苯并二氢吡喃-4-酮についての法規ガイドラインは何ですか?
6-硝基苯并二氢吡喃-4-酮(CAS番号: 68043-53-8)は、GHS(統一化された化学品の危険性的分類と標識)で急性毒性第4クラスに分類されます。EUで...
6-乙酰基-2(3H)-苯并噻唑酮は安全ですか?
安全性は化合物の使用方法によります。適切な取扱いと防護措置を講じれば、一定の安全性があります。ただし、吸入や皮膚への接触は避けてください。
3-メチル-6-(1-メチルヒドラジニル)ピリジジンはどの業界で使用されていますか?
3-メチル-6-(1-メチルヒドラジニル)ピリジジンは主に医薬品、ポリマー、センサー製造業界で使用されています。特に、医薬品産業では抗がん剤や抗真菌剤の候補物質...
tert-butyl 5-oxo-2,6-diazaspiro[3.4]octane-2-carboxylateの物理化学的性質は何ですか?
tert-butyl 5-オキソ-2,6-ジアザスパイロ[3.4]オクタネ-2-カルボキサongyangはCAS番号1330765-39-3で、分子量は334....
3-塩素メチルフェニル-4,4,5,5-テトラメチル-1,3,2-ジオキソボロラノールは安全ですか?
3-塩素メチルフェニル-4,4,5,5-テトラメチル-1,3,2-ジオキソボロラノールは、毒性が低いと考えられていますが、直接的な皮膚接触や吸入は避けるべきです...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
![Benzeneacetic acid, 2-[(2,6-dichlorophenyl)amino]-, compd. with 1-pyrrolidineethanol (1:1) structure Benzeneacetic acid, 2-[(2,6-dichlorophenyl)amino]-, compd. with 1-pyrrolidineethanol (1:1) structure](https://static.chemtradehub.com/structs/119/119623-66-4-5301.webp)



