Visible light-mediated atom transfer radical addition to styrene: base controlled selective (phenylsulfonyl)difluoromethylation

文献情報

出版日 2020-01-10

DOI 10.1039/C9QO01433K

インパクトファクター 5.281

著者

Jie Sheng, Kang-Jie Bian, Yi-Ming Su, Guang-Xu Liao, Ruomeng Duan, Chen Li, Zhihong Liu, Xi-Sheng Wang

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要旨

The first example of a visible light-mediated atom transfer radical addition reaction of (phenylsulfonyl)difluoromethyl iodide to styrenes has been reported. By simply tuning the organic or inorganic bases in the reaction system, both ATRA and heck-type products could be afforded with high selectivity. This method has demonstrated mild conditions, high catalytic reactivity, excellent chemoselectivity and a broad substrate scope. Besides, it offers a new solution for difunctionalization of alkenes to synthesize diverse difluoromethylated molecules after a simple work-up.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Visible light-mediated atom transfer radical addition to styrene: base controlled selective (phenylsulfonyl)difluoromethylation

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