Oxalatocuprate(ii) hexaammincobalt(iii) as a precursor of metastable solid solutions in the Co–Cu system

文献情報

出版日 2024-01-03

DOI 10.1039/D3NJ05311C

インパクトファクター 3.591

著者

Varvara Lagunova, Evgeny Filatov, Pavel Plyusnin, Natalia Kuratieva, Sergey Korenev

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要旨

The synthesis and characterization of the double complex salts [Co(NH3)6]2[Cu(C2O4)2]3·4H2O and [Co(NH3)6]2[Cu(C2O4)2]3·6H2O was carried out. The process of thermal decomposition of synthesized compounds in reducing and inert atmospheres was studied with determination of the released gases composition, as well as intermediate and final decomposition products by ex situ XRD. The thermal decomposition of complex salts in reducing and inert atmospheres was studied by in situ powder X-ray diffraction on a laboratory diffractometer. The possibility of the formation of metastable solid solutions in the Co–Cu system with a maximum copper content up to 37 at% was demonstrated.

掲載誌

New Journal of Chemistry

CiteScore: 5.3

自己引用率: 3.7%

年間論文数: 2153

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.

Oxalatocuprate(ii) hexaammincobalt(iii) as a precursor of metastable solid solutions in the Co–Cu system

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New Journal of Chemistry

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