Copolymers of 2-hydroxyethylacrylate and 2-methoxyethyl acrylate by nitroxide mediated polymerization: kinetics, SEC-ESI-MS analysis and thermoresponsive properties

文献情報

出版日 2011-09-27

DOI 10.1039/C1PY00344E

インパクトファクター 5.582

著者

Anna-Marie Zorn, Helmut Keul, Christopher Barner-Kowollik, Martin Moeller

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要旨

The nitroxide mediated copolymerization of 2-hydroxyethyl acrylate (HEA) and 2-methoxyethyl acrylate (MEA) is reported. The copolymerization kinetics followed the persistent radical model and revealed the formation of well-defined ideal random copolymers (rHEA = 0.93 ± 0.09; rMEA = 0.95 ± 0.09). SEC-ESI-MS proved the presence of both the initiation fragment and SG1 as chain ends of the polymers. The cloud point temperature of the copolymers increased from 5 °C and 60 °C with increasing HEA content from 0% to 70% and they are discussed in relation to both monomer and end-group structure.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Copolymers of 2-hydroxyethylacrylate and 2-methoxyethyl acrylate by nitroxide mediated polymerization: kinetics, SEC-ESI-MS analysis and thermoresponsive properties

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