A desulphurization strategy for Sonogashira couplings by visible light/copper catalysis

文献情報

出版日 2021-12-02

DOI 10.1039/D1QO01548F

インパクトファクター 5.281

著者

Xuan Li, Xiaolong Zhu, Xiuyan Song, Qirong Deng, Jian Lv

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要旨

The development of new copper-based catalysts in photoredox transformations has become a rapidly growing area of research and has been actively explored in the past several years. Herein, we have developed a new copper-based catalyst, [(binap)(tpy)Cu]Cl, and applied it in the visible-light promoted Sonogashira coupling reactions. This mild protocol results in various substituted alkynes from simple sulfonium salts which can be easily prepared from commercially available and inexpensive thiols, alcohols, and alkyl halides. This study will broaden the still limited strategies of copper photocatalysts in organic transformations.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

A desulphurization strategy for Sonogashira couplings by visible light/copper catalysis

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