Switchable hydroxysulfonyloxylation and defluorination–decarboxylation sulfonylation of gem-difluoroalkenes with sodium sulfinate via aerobic oxidation

文献情報

出版日 2021-09-03

DOI 10.1039/D1QO01005K

インパクトファクター 5.281

著者

Xiang Liu, Jiatong Lin, Canzhan Zhuang, Jinling Zhong, Dan Song, Jiaji Zhao, Hua Cao

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要旨

A novel and attractive aerobic oxidative hydroxysulfonyloxylation of gem-difluoroalkenes with sodium sulfinate via free radical addition has been developed. In addition, successive defluorination–decarboxylation sulfonylation of gem-difluoroalkenes in the presence of Et3N·3HF is realized. These transformations present dual capacity of molecular oxygen and sodium sulfinate, furnishing difluoroalkyl sulfonates and sulfone derivatives under metal-free and mild conditions.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Switchable hydroxysulfonyloxylation and defluorination–decarboxylation sulfonylation of gem-difluoroalkenes with sodium sulfinate via aerobic oxidation

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