Synthesis and anionic polymerization of isosorbide mono-epoxides for linear biobased polyethers

文献情報

出版日 2021-10-12

DOI 10.1039/D1PY00687H

インパクトファクター 5.582

著者

Livia Matt, Ilme Liblikas, Olivier Bonjour, Lauri Vares

原文を見る

要旨

A series of regioisomeric isosorbide mono-epoxides, as well as diastereomerically pure mono-epoxy derivatives, have been prepared and studied. Anionic ring-opening polymerization of methoxy-capped monomers produced linear polyethers tethered with isosorbide units. These reasonably high molecular weight polymers exhibited glass transition temperatures at around 10–15 °C and thermal stability up to ∼300 °C, which indicated that the mono-epoxides are promising building blocks for well-defined biobased polymers.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Synthesis and anionic polymerization of isosorbide mono-epoxides for linear biobased polyethers

文献情報

おすすめジャーナル

関連文献

Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes

A total loss of innocence: double ortho-metallation of bis(triphenylphosphano)iminium cation, [N(PPh3)2]+, by tris(η-naphthalene)tantalate(1−)‡

Crystallographic characterization and identification of a minor isomer of C84fullerene

Contents and Chemical Biology

Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of TiNNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

Highly enantio- and diastereoselective organocatalytic cascade aza-Michael–Michael reactions: a direct method for the synthesis of trisubstituted chiral pyrrolidines

Greatly reduced amino acid alphabets in directed evolution: making the right choice for saturation mutagenesis at homologous enzyme positions

99m-Technetium carbohydrate conjugates as potential agents in molecular imaging

Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

One-pot solvothermal synthesis of FePt/Fe3O4 core–shell nanoparticles

こちらもおすすめ

S-(甲硅烷基丙基)異硫酰氯を取り扱う際の実験室安全事項は何ですか？

8-硝基-咪唑并[1,2-a]吡啶とは何ですか？

4-ブロモ-5-メトキシピリジン-2-甲醇の代替品はありますか？

全氟-1,2-二甲基環己烷を含む廃棄物はどのように処理すべきですか？

3-(溴甲基)苯乙酸の主な用途は何ですか？

5-イドキド-4-メチオキシ-6-メチルピリミジニン-2-アミンはどのように保存すればよいですか？

1-(2-溴-6-甲氧基苯基)乙酮を取り扱う際の実験室安全事項は何ですか？

5-(4,4,5,5-テトラメチル-1,3,2-ダイオキサボラロール-2-イル)-1,3-ジヒドロ-2-ベンゾフランは安全ですか？

4-溴萘-1-甲酸の代替品はありますか？

ε-白藜芦醇脱氢二聚体の代替品はありますか？

掲載誌

Polymer Chemistry

おすすめ化合物

8-Fluoroquinazoline-2,4(1H,3H)-dione

tert-butyl N-(5-methylpyrazin-2-yl)carbamate

Sepiolite (Mg4(OH)2(Si2O5)3.6H2O)

2-Methyl-2-propanyl 4-{2-fluoro-5-[(4-oxo-3,4-dihydro-1-phthalazinyl)methyl]benzoyl}-1-piperazinecarboxylate

5,5'-Bis(trifluoromethyl)-2,2'-bipyridine

おすすめサプライヤー