Striking solvent dependence of total emission and circularly polarised luminescence in coordinatively saturated chiral europium complexes: solvation significantly perturbs the ligand field
文献情報
Jack D. Fradgley, Andrew T. Frawley, Robert Pal, David Parker
Examination of total emission and circularly polarised luminescence (CPL) spectra of three 9-coordinate Eu(III) complexes with well-defined speciation shows that the ligand fields of these C3 symmetric complexes are extremely sensitive to solvent polarity, even when solvent is not present in the first coordination sphere. The energies, intensities, and (for CPL) the sign of some transitions vary with solvent polarity. These observations are rationalised by analysis of the factors that control total and circularly polarised emission, and have important implications for design of responsive luminescent Ln(III) probes.
関連文献
Sign inversion of surface stress–charge response of bulk nanoporous nickel actuators with different surface states
Qingguo Bai, Conghui Si, Jie Zhang, Zhonghua Zhang
DOI: 10.1039/C6CP02535H
Exploring the core level shift origin of sulfur and thiolates on Pd(111) surfaces
Roberto Carlos Salvarezza, Pilar Carro
DOI: 10.1039/C5CP04180E
A computational study on the N-heterocyclic carbene-catalyzed Csp2–Csp3 bond activation/[4+2] cycloaddition cascade reaction of cyclobutenones with imines: a new application of the conservation principle of molecular orbital symmetry
Yang Wang, Bohua Wu, Haoyang Zhang, Donghui Wei, Mingsheng Tang
DOI: 10.1039/C6CP03180C
Self-diffusion, velocity cross-correlation, distinct diffusion and resistance coefficients of the ionic liquid [BMIM][Tf2N] at high pressure
Kenneth R. Harris, Mitsuhiro Kanakubo
DOI: 10.1039/C5CP04277A
Energy landscapes of a hairpin peptide including NMR chemical shift restraints
Joanne M. Carr, Chris S. Whittleston, David C. Wade, David J. Wales
DOI: 10.1039/C5CP01259G
Study of the interface between Na-rich and Li-rich phases in a Na-inserted spinel Li4Ti5O12 crystal for an electrode of a sodium-ion battery
Mitsunori Kitta, Riki Kataoka, Masanori Kohyama
DOI: 10.1039/C6CP03379B
Regeneration mechanisms of high-lithium content zirconates as CO2 capture sorbents: experimental measurements and theoretical investigations
Yuhua Duan
DOI: 10.1039/C5CP03968A
Computational screening for effective Ge1−xSix nanowire photocatalyst
Teck L. Tan, Man-Fai Ng
DOI: 10.1039/C5CP03077C
Facile synthesis of core/shell ZnO/ZnS nanofibers by electrospinning and gas-phase sulfidation for biosensor applications
Kamil Sobczak, Piotr Dłużewski, Anna Reszka, Bogdan J. Kowalski, Łukasz Kłopotowski, Danek Elbaum, Krzysztof Fronc
DOI: 10.1039/C5CP02278A
Re-examining the Chevrel phase Mo6S8 cathode for Mg intercalation from an electronic structure perspective
Florian Thöle, Liwen F. Wan, David Prendergast
DOI: 10.1039/C5CP03046C
こちらもおすすめ
2-メトキシ-4-(メチルスルフィニル)アミンの主な用途は何ですか?
2-メトキシ-4-(メチルスルフィニル)アミンは、主に医薬品および農薬の製造に使用されます。また、合成化学の一部として研究用材料としても利用されます。
4,6-二氯-N-甲基ピラミジンアミンの代替品はありますか?
代替品としては、4,6-二クロロピラミジンアミンや他のピラミジン系化合物が考えられます。ただし、目的と用途によって最適な代替品は異なります。
6-氯-4-甲基-1H-吲哚を含む廃棄物はどのように処理すべきですか?
6-氯-4-甲基-1H-吲哚の廃棄物は、適切な容器に収集し、密閉して保管します。温度は常温、湿度は低く、直射日光を避けて保管することを推奨します。廃棄処理は専門...
2-フローユロ-4-(トリフルオロメチル)ベンゾイドについて「に適用される法規ガイドラインは何ですか」
2-フローユロ-4-(トリフルオロメチル)ベンゾイドのCAS番号は207974-08-1です。この化合物はGHS分類で毒性物質と有害な反応物質として分類されます...
4-ニトロフェニルN-[(ベンゼルオキシルカーボンイル]グリシングリシングリシン酸はどのように保存すればよいですか?
4-ニトロフェニルN-[(ベンゼルオキシルカーボンイル]グリシングリシングリシン酸は、室温で暗所に保管し、乾燥した環境で保存することを推奨します。容器は密閉性の...
イソデスロラタドリンの代替品はありますか?
イソデスロラタドリンの代替品としては、デスロラタドリンや他の抗ヒスタミン薬が挙げられます。具体的には、デスロラタドリン、ラセカミド、フェルタドリンなどが、症状や...
5-甲氧基-1,2,3,4-四氢异喹啉盐酸盐はどのように合成されますか?
5-甲氧基-1,2,3,4-四氢异喹啉盐酸盐の一般的な合成方法は、メタノール中で5-メトキシ-1,2,3,4-四ヒュドロイソキシンを塩酸で塩化します。この反応で...
4-アミノ-5-メトキシ-2-トルエンサルホニック酸についての法規ガイドラインは何ですか?
CAS番号6471-78-9の4-アミノ-5-メトキシ-2-トルエンサルホニック酸は、GHS分類では corrosive(腐食性)と識別されます。EUのREAC...
甲基孕酮を取り扱う際の実験室安全事項は何ですか?
甲基孕酮の取り扱いは、PPE(個人保護具)の使用が必要な重要な安全事項を伴います。防塵マスク、ゴーグル、手袋を着用することが推奨されます。ドラフトチャンバーを使...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid structure [(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid structure](https://static.chemtradehub.com/structs/509/50918-26-8-4ce8.webp)


