Practical copper-catalyzed chloronitration of alkenes with TMSCl and guanidine nitrate

文献情報

出版日 2020-07-20

DOI 10.1039/D0QO00691B

インパクトファクター 5.281

著者

Si-Yuan Li, Zhen-Yu Guan, Jing Xue, Guang-Yi Zhang, Xiao-Yu Guan, Qing-Hai Deng

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要旨

A novel and practical chloronitration of alkenes in the presence of easily available TMSCl and guanidine nitrate has been developed by using cheap copper sulfate pentahydrate as the catalyst. A variety of vic-chloronitro compounds were directly synthesized in good to excellent yields on up to 100 mmol scale under mild reaction conditions, and the resulting products could be smoothly transformed into the corresponding nitroalkenes and diverse nitro compounds bearing a vicinal nucleophilic “C”, “N” or “S” unit.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Practical copper-catalyzed chloronitration of alkenes with TMSCl and guanidine nitrate

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