Jahn–Teller effect in LiMn2O4: influence on charge ordering, magnetoresistance and battery performance

文献情報

出版日 2016-12-12

DOI 10.1039/C6CP07289E

インパクトファクター 3.676

著者

K. Ragavendran, H. Xia, P. Mandal, A. K. Arof

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要旨

The phase transition near room temperature in LiMn2O4 was studied using thermal expansion measurements, and directly compared with the electrochemical performance of the material. Studies based on thermal expansion indicate the onset of a first-order phase transition at Tc ∼ 220 K for the nearly half-doped material, with [Mn3+]/[Mn4+] ≈ 1. The Tc shifts to a higher temperature, ∼290 K, and signatures for Verwey-type charge ordering at 290 K can be observed when the fraction of Jahn–Teller Mn3+ in LiMn2O4 is increased, i.e., [Mn3+]/[Mn4+] > 1. These studies show that the first-order phase transition near room temperature in LiMn2O4 is associated with charge ordering, which ultimately is a consequence of the Jahn–Teller effect. In addition, the Jahn–Teller effect is proven to be an important cause of magnetoresistance and electrochemical capacity fading in LiMn2O4. Electrochemical measurements show that both materials, either with a Tc ∼ 220 K or Tc ∼ 290 K, exhibit capacity fading to almost the same extent. Electrochemical capacity retention is observed only in nanosized LiMn2O4, for which the phase transition anomalies are completely absent.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Jahn–Teller effect in LiMn2O4: influence on charge ordering, magnetoresistance and battery performance

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