Visible light enabled para-fluoro-thiol ligation

文献情報

出版日 2020-10-31

DOI 10.1039/D0PY01373K

インパクトファクター 5.582

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要旨

Herein, we demonstrate a light-induced para-fluoro-thiol reaction using the photogeneration of a superbase, i.e. 1,8-diazabicyclo[5.4.0]undec-7-ene. This photochemical process was utilized in the synthesis of small thioether molecules with high yields (>85%), and the side-chain modification and crosslinking of a poly(styrene-co-pentafluorostyrene). The reaction can be triggered by visible light with temporal control, enabling the use of sunlight for activation.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Visible light enabled para-fluoro-thiol ligation

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