Cationic polymerization of vinyl monomers using halogen bonding organocatalysts with varied activity

文献情報

出版日 2020-10-09

DOI 10.1039/D0PY01207F

インパクトファクター 5.582

著者

Koji Takagi, Hiroto Murakata, Koji Yamauchi, Kohei Hashimoto

原文を見る

要旨

By using non-ionic and multidentate halogen bonding organocatalysts, the cationic polymerization of IBVE was investigated to reveal the relationship between the catalytic activity and the substitution pattern of halogen bond donor units with the aid of theoretical calculation. The polymerization successfully proceeded at room temperature using an appropriate catalyst. The polymerization of other vinyl ethers and styrene derivatives was also investigated in the presence of ionic organocatalysts to figure out that the coordination ability of the counter anion significantly affected the catalytic activity. In particular, the polymerization of pMOS occurred in a controlled manner enabling the molecular weight regulation by ca. Mn = 10 000.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Cationic polymerization of vinyl monomers using halogen bonding organocatalysts with varied activity

文献情報

おすすめジャーナル

関連文献

Coarse-grained simulations of ionic liquid materials: from monomeric ionic liquids to ionic liquid crystals and polymeric ionic liquids

Multiscale structural and rheological features of colloidal low-methoxyl pectin solutions and calcium-induced sol–gel transition

Back cover

Activation of CO2 and CH4 on MgO surfaces: mechanistic insights from first-principles theory

Generalized energy-based fragmentation approach for calculations of solvation energies of large systems

A new universal force-field for the Li2S–P2S5 system

Discerning phase-matrices for individual nitride inclusions within ultra-high-strength steel: experiment driven DFT investigation

Investigation of crystallization kinetics and its relationship with molecular dynamics for chiral fluorinated glassforming smectogen 3F5HPhH6

ReaxFF-MPNN machine learning potential: a combination of reactive force field and message passing neural networks

Single-nanoparticle spectroelectrochemistry studies enabled by localized surface plasmon resonance

こちらもおすすめ

間溴苯甲酰腈の市場動向や研究トレンドはどうですか？

去磺基萝卜硫苷とは何ですか？

Methyl 2-amino-5-(trifluoromethyl)benzoateに適用される法規ガイドラインは何ですか？

3-ブロモ-1,3,4,5-四水化-2H-1-ベンザアゼピン-2-オンは安全ですか？

三氟甲基ピリジン-2-甲アミン塩酸塩は安全ですか？

1-エチル-4-(4-硝基フェニル)ピペリジンは安全ですか？

1,1-ジメトキシプロパン-2-オンは安全ですか？

コバルト(II) 3,3'-{[(1S,2S)-1,2-ジメチルフENCYCLICALE-1,2-エチエンジイル]ビス[ニトロリルメチルイリデン]}ビス[4-オキソ-2-ペンテン-2-olate]について「に適用される法規ガイドラインは何ですか？

「カーバミル酸, N-[8-[[2-[[2-(2,6-ジオキソ-3-ピペリジニル)-2,3-ジオキソ-1,3-ジヒドロ-1H-イソイソインドール-4-イルオキシ]アセチル]アミノ]オクチル]-1,1-ジメチレチルエステル」はどのように保存すればよいですか？

FMoc-D-4-Aph(tBu-CbM)-OHはどのように保存すればよいですか？

掲載誌

Polymer Chemistry

おすすめ化合物

2-Hydroxy-3-methoxy-5-nitrobenzaldehyde

3,3-Dimethoxy-2-butanone

Cistanoside F

2,6-Difluoro-4-iodopyridine

DL-alanyl-DL-valine

おすすめサプライヤー