Nickel(ii)-catalyzed C(sp2)–H sulfuration/annulation with elemental sulfur: selective access to benzoisothiazolones

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出版日 2019-04-27

DOI 10.1039/C9OB00449A

インパクトファクター 3.876

著者

Jun-Ru Guo, Jun-Fang Gong, Mao-Ping Song

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要旨

The first nickel(II)-catalyzed direct sulfuration/annulation of C(sp2)–H bonds with elemental sulfur has been achieved by using 2-amino alkylbenzimidazole (MBIP-amine) as a N,N-bidentate directing group. This strategy tolerates a wide range of functional groups, furnishing structurally diverse benzoisothiazolone derivatives with benzimidazole skeletons in moderate to excellent yields in a simple and efficient way.

掲載誌

Organic & Biomolecular Chemistry

CiteScore: 3.4

自己引用率: 10.3%

年間論文数: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Nickel(ii)-catalyzed C(sp2)–H sulfuration/annulation with elemental sulfur: selective access to benzoisothiazolones

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