Synthesis of corrugated C-based nanostructures by Br-corannulene oligomerization
文献情報
Marco Smerieri, Lara Ferrighi, Silvia Nappini, Luca Vaghi, Antonio Papagni, Cristiana Di Valentin, Federica Bondino, Letizia Savio
The structure and electronic properties of carbon-based nanostructures obtained by metal surface assisted synthesis is highly dependent on the nature of the precursor molecule. Here, we report on a combined scanning tunneling microscopy, soft X-ray spectroscopy and density functional theory investigation on the surface assisted polymerization of Br-corannulene at Ag(110) and on the possibility of building a mesh of π-conjugated polymers starting from buckyball shaped molecules. Indeed, the corannulene units form one-molecule-wide ribbons in which the natural concavity of the precursor molecule is maintained. These C-based nanostructures are corrugated and merge into a covalent network on the surface.
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