I2-Catalyzed sulfenylation of indoles and pyrroles using triethylammonium thiolates as sulfenylating agents

文献情報

出版日 2017-02-20

DOI 10.1039/C6QO00851H

インパクトファクター 5.281

著者

Wei Fan, Zhen Yang

原文を見る

要旨

Readily available triethylammonium thiolates were proved to be new and eco-friendly sulfenylating agents for the efficient and practical construction of sulfenylated indoles and pyrroles (48 examples) with good to excellent yields under metal-free and microwave irradiation conditions. The combination of I2 and DMSO enabled direct C–S bond formation, allowing easy and low-cost access to new functionalized C,S-tethered bisindoles and pyrrole–indole pairs with a wide diversity of substituents. The mechanism involving S–S and S–I bond-forming/breaking events was proposed.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

I2-Catalyzed sulfenylation of indoles and pyrroles using triethylammonium thiolates as sulfenylating agents

文献情報

おすすめジャーナル

関連文献

Synthesis and charge-transporting properties of electron-deficient CN2–fluorene based D–A copolymers

Contents list

Imidazole-accelerated crosslinking of epoxidized natural rubber by dicarboxylic acids: a mechanistic investigation using NMR spectroscopy

Rapidly thiol-responsive degradable block copolymer nanocarriers with facile bioconjugation

Three new conjugated polymers based on benzo[2,1-b:3,4-b′]dithiophene: synthesis, characterization, photoinduced charge transfer and theoretical calculation studies

Contents list

ATRP–RCMpolymercyclization: synthesis of amphiphilic cyclic polystyrene-b-poly(ethylene oxide) copolymers

Back matter

Degradable graft copolymers by ring-opening and reverse addition–fragmentation chain transfer polymerization

A new story of cyclodextrin as a bulky pendent group causing uncommon behaviour to random copolymers in solution

こちらもおすすめ

6- bromo-1-cyclopropyl-1H-benzimidazoleの市場動向や研究トレンドはどうですか？

環氧プロpanol-d5を取り扱う際の実験室安全事項は何ですか？

2,2’-ジメチル-3,3’-ビピリジンはどのように合成されますか？

6-甲基ピリジン-2-ボリック酸の主な用途は何ですか？

（R）-3-(1-甲基-2-氧環己基)プロpano酸メチルは安全ですか？

ketorolacはどのように保存すればよいですか？

L-2,3-二氨基丙酸二盐酸盐を取り扱う際の実験室安全事項は何ですか？

2-(4-溴ピリジン-2-基)乙腈の物理化学的性質は何ですか？

3-フローロ-[1,1-ベンジレン]-3,4-ジカルボン酸を取り扱う際の実験室安全事項は何ですか？

3-(1-氧代-1,3-二氢-2H-2-异吲哚)丙酸の主な用途は何ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

Benzyl 3-bromoazetidine-1-carboxylate

3,4-Dichlorobiphenyl

6,7-Dibromo-2,3-dihydro-1,4-benzodioxine

5-(3,4-Dimethoxybenzyl)-2,4-pyrimidinediamine hydrochloride (1:1)

6-Bromo-2,3-dihydro-1H-pyrido[2,3-b][1,4]oxazine

おすすめサプライヤー