100% hyperbranched polymers via the acid-catalyzed Friedel–Crafts aromatic substitution reaction

文献情報

出版日 2016-07-29

DOI 10.1039/C6PY01168C

インパクトファクター 5.582

著者

Dong Yang, Jie Kong

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要旨

A highly efficient and benign strategy to synthesize hyperbranched polymers with a degree of branching of 100% was presented via a Friedel–Crafts aromatic substitution reaction of an AB2 monomer, 5-(4-phenoxyphenoxy)isobenzofuran-1,3-dione, in the presence of trifluoromethanesulfonic acid. The molecular weight (Mw: 66.1–294.8 kDa) and the polydispersity (close to 2.0) can be tuned by controlling polymerization conditions. It makes it convenient to tailor hyperbranched polymers for potential application in functional materials.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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100% hyperbranched polymers via the acid-catalyzed Friedel–Crafts aromatic substitution reaction

文献情報

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