Diastereoselective formation of a dipalladium(i) complex supported by a bridging tetradentate ligand, and oxidative addition of RS–H across a phosphine-bridged PdI–PdI bond

文献情報

出版日 2003-03-20

DOI 10.1039/B300177F

インパクトファクター 6.222

著者

S. Jo Ling Foo, Nathan D. Jones, Brian O. Patrick, Brian R. James

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要旨

The ligand CH2(P(o-C6H4NMe2)2)2 (dmapm) gives access to the first example of a dipalladium(I) complex supported by a tetradentate ligand, Pd2Cl2(μ-N,P,P,N-dmapm), which, unlike the well-known Pd2X2(μ-dppm)2 complexes (X = halide, dppm = bis(diphenylphosphino)methane), reacts with thiols to give addition of RS–H across a phosphine-bridged Pd–Pd bond.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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Diastereoselective formation of a dipalladium(i) complex supported by a bridging tetradentate ligand, and oxidative addition of RS–H across a phosphine-bridged PdI–PdI bond

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