Activated carbonates: enabling the synthesis of differentiated polycarbonate resins via melt transcarbonation

文献情報

出版日 2016-08-05

DOI 10.1039/C6PY00925E

インパクトファクター 5.582

著者

T. Hoeks, E. Kung, J. P. Lens, P. J. McCloskey, B. A. J. Noordover, J. P. A. Heuts

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要旨

Activated carbonates facilitate the preparation of polycarbonates based on monomers that are unsuitable for traditional melt polymerization at high temperatures. Bis(methyl salicyl) carbonate (BMSC) clearly shows reactivity benefits over diphenyl carbonate in melt polymerization reactions, resulting in shorter reaction times and reduced heat exposure during polymerization. The increased reactivity enables the melt polymerization of a wide range of monomers, as demonstrated by two examples using volatile resorcinol and sterically hindered tert-butyl hydroquinone as monomers in the preparation of (co)polycarbonates.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Activated carbonates: enabling the synthesis of differentiated polycarbonate resins via melt transcarbonation

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