Tailoring the structure of polymer networks with iniferter-mediated photo-growth

文献情報

出版日 2016-04-01

DOI 10.1039/C6PY00325G

インパクトファクター 5.582

著者

Awaneesh Singh, Olga Kuksenok, Jeremiah A. Johnson, Anna C. Balazs

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要旨

Using dissipative particle dynamics (DPD), we developed a computational approach to capture the photo-controlled radical polymerization (“photo-growth”) of polymer gels containing trithiocarbonate (TTC) groups within the network strands. Using this model, we focused on a “primary gel” and illuminated the sample to activate the TTCs, which then interacted with monomer and cross-linker in the solution. At low TTC concentrations, gels composed of compatible monomers formed two distinct, spatially separated layers. Conversely, at high TTC concentration, gels formed from incompatible components displayed a well-intermixed structure. Hence, in the presence of light, variations in the TTC concentration provide a new approach for controllably tailoring the structure of polymer gels, and thereby tailoring the functionality of the network.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Tailoring the structure of polymer networks with iniferter-mediated photo-growth

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