Colored single-chain polymeric nanoparticles via intramolecular copper phthalocyanine formation

文献情報

出版日 2015-02-19

DOI 10.1039/C4PY01559B

インパクトファクター 5.582

著者

Jonghwa Jeong, Yun-Jung Lee, Bohyun Kim, Byoungjae Kim, Ki-Suck Jung, Hyun-jong Paik

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要旨

We have synthesized single-chain polymeric nanoparticles through the intramolecular formation of copper phthalocyanines from polystyrene-co-poly[4-((4-vinylbenzyl)oxy)phthalonitrile] under diluted conditions. Linear copolymer precursors carrying phthalonitrile pendant groups were prepared by reversible addition–fragmentation chain transfer (RAFT) polymerization followed by intramolecular macrocyclization reactions to form Cu-metallated phthalocyanines, which concurrently enabled single chain nanoparticle formation. The preparation of copper phthalocyanines within a single chain nanoparticle was confirmed using FT-IR and UV/Vis spectroscopy. The intramolecular chain collapse was characterized by SEC and AFM.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Colored single-chain polymeric nanoparticles via intramolecular copper phthalocyanine formation

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