Formation and evolution of the unexpected PbI2 phase at the interface during the growth of evaporated perovskite films
文献情報
Haitao Xu, Yanglin Wu, Jian Cui, Chaowei Ni, Fuzong Xu, Jiang Cai, Feng Hong, Zebo Fang, Wenzhen Wang, Linjun Wang, Run Xu
The interface chemistry and evolution of the evaporated perovskite films on ITO, pedot/ITO, Si and glass substrates are studied. As evidenced by X-ray diffraction and X-ray photoemission spectroscopy (XPS) results, the PbI2 phase is found to be inevitably formed at the very initial growth stage, even under the conditions of a MAI-rich environment. The extremely low binding energy of adsorbed MAI particles on all the above substrates, as compared to that of PbI2 particles, is responsible for the presence of the PbI2 phase at the interface. The formation of both hole and electron barriers at the interface of PbI2/MAPbI3, as evidenced by XPS measurements, could block carrier transport into the electrode and thus deteriorate solar cell performance. This result reveals the origin of the poor performance of perovskite solar cells (PSCs) by the vacuum evaporation method, and may help to improve the performance of PSCs made using the vacuum evaporation method.
関連文献
Synthetic strategies for the generation of ABCA' type asymmetric tetrablock terpolymers
Siddharth Chanpuriya, Marc A. Hillmyer, Frank S. Bates
DOI: 10.1039/C4PY00614C
Ultra-sensitive detection of explosives in solution and film as well as the development of thicker film effectiveness by tetraphenylethene moiety in AIE active fluorescent conjugated polymer
Khama Rani Ghosh, Sukanta Kumar Saha
DOI: 10.1039/C4PY00673A
Unprecedented cucurbituril-based ternary host–guest supramolecular polymers mediated through included alkyl chains
Nana Sun, Dongdong Qi, Jianzhuang Jiang
DOI: 10.1039/C4PY00512K
Preparation of sulfonic acid functional proton conducting phosphazenes by covalent protection
Ferda Hacıvelioğlu
DOI: 10.1039/C7PY00189D
Nanocomposite latexes containing layered double hydroxides via RAFT-assisted encapsulating emulsion polymerization
Ana Cenacchi Perreira, Samuel Pearson, Franck D'Agosto, Muriel Lansalot, Elodie Bourgeat-Lami
DOI: 10.1039/C6PY01742H
Conformation pre-organization in fluorene-based conjugated polymer for simultaneous enhancement of luminescence and charge mobility
Juxin He, Luyang Du, Cong Wang, Mingjian Jiang, Linlin Liu, Yueqi Mo, Zengqi Xie, Bing Yang, Yuguang Ma
DOI: 10.1039/C6PY01995A
Oxygen and carbon dioxide dual gas-responsive homopolymers and diblock copolymers synthesized via RAFT polymerization
Xue Jiang, Guolin Lu, Huang Xiaoyu
DOI: 10.1039/C6PY02004F
Dual-stimuli responsive liposomes using pH- and temperature-sensitive polymers for controlled transdermal delivery
Takumi Sugimoto, Mitsuhiro Fukushima, Ryoma Teranishi, Aki Kotaka, Chiharu Shinde, Takayuki Kumei, Yasushi Sumida, Yuki Munekata, Kei-ichi Maruyama, Eiji Yuba, Atsushi Harada, Kenji Kono
DOI: 10.1039/C6PY01754A
Effect of epoxy monomer structure on the curing process and thermo-mechanical characteristics of tri-functional epoxy/amine systems: a methodology combining atomistic molecular simulation with experimental analyses
Liang Gao, Qingjie Zhang, Hao Li, Siruo Yu, Weihong Zhong, Gang Sui, Xiaoping Yang
DOI: 10.1039/C7PY00063D
Controlling the folding of conjugated polymers at the single molecule level via hydrogen bonding
Beiyue Shao, Xinju Zhu, Kyle N. Plunkett, David A. Vanden Bout
DOI: 10.1039/C6PY01871H
こちらもおすすめ
5-苄基四氢吡咯并[3,4-c]吡咯-1,3[2H,3ah]-二酮の主な用途は何ですか?
5-苄基四氢吡咯并[3,4-c]吡咯-1,3[2H,3ah]-二酮は、主に薬理学的研究と合成化学に使用されます。また、特定の医薬品の合成原材料としても利用されま...
唾液酸路易ス Aを取り扱う際の実験室安全事項は何ですか?
唾液酸路易ス Aの取り扱いでは、個別の防護具(PPE)が必要で、手袋、顔面保護具、防塵マスクを着用します。ドラフトチャンバーを使用し、漏洩時の適切な処理を行うこ...
タルトブチル ((1-(2-クロロアセチル)ピペリジン-4-イルメチル)カーバamatはどの業界で使用されていますか?
タルトブチル ((1-(2-クロロアセチル)ピペリジン-4-イルメチル)カーバamatは、医薬品業界、ポリマー業界、センサー技術、半導体業界などで使用されていま...
3-烯丙基-2-羟基苯甲醛の物理化学的性質は何ですか?
3-烯丙基-2-羟基苯甲醛のCAS番号は24019-66-7です。物化性質としては、白色結晶性粉末で、分子量は174.22です。この化合物は水に溶けやすく、反応...
乳清酸 Potassium Orotateとは何ですか?
乳清酸 Potassium Orotateは、CAS番号24598-73-0の化合物で、乳清酸と Potassium(カリウム)による塩基です。化学式はC7H7...
4-甲基苯磺酸异丙酯はどの業界で使用されていますか?
4-甲基苯磺酸异丙酯は医薬品業界で広く使用されています。また、ポリマーの増塑剤や半導体製造におけるセンサー材料としても使用されることがあります。
6-(3- Florobenzen)-N-[1-(2,2,2- Trifluoroethyl)-4-Piperidinyl]-3-Pyridinycarboxamideはどの業界で使用されていますか?
6-(3-氟苯基)-N-[1-(2,2,2-三氟乙基)-4-哌啶基]-3-吡啶羧酰胺は医薬品産業で広く使用されており、その特性は抗炎症作用や抗ウイルス作用など、...
左西孟旦はどのように合成されますか?
左西孟旦は、3-[(2-メチルフェニル)-2-(4-メチルフェニル)-1-オキシエチル]-1,2,4-トリTürkiyeン-5-カルボン酸と4-メチルフェニル-...
3-乙氧基哌啶盐酸盐に適用される法規ガイドラインは何ですか?
CAS番号1159826-79-5の3-乙氧基哌啶盐酸盐は、GHS分類ではイエローカテゴリーに分類され、毒性物質として扱われます。REACH規則では、製造または...
Diethyl (hydroxymethyl)phosphonateの主な用途は何ですか?
Diethyl (hydroxymethyl)phosphonateは、医薬品の製造や農薬、合成化学の一部として利用されます。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![N-[(1R,2R)-2-Amino-1,2-diphenylethyl]-1,1,1-trifluoromethanesulfonamide structure N-[(1R,2R)-2-Amino-1,2-diphenylethyl]-1,1,1-trifluoromethanesulfonamide structure](https://static.chemtradehub.com/structs/852/852212-89-6-5ef9.webp)
![2-[1-(4-Chlorobenzyl)-1H-indol-3-yl]-2-oxo-N-(6-quinolinyl)acetamide structure 2-[1-(4-Chlorobenzyl)-1H-indol-3-yl]-2-oxo-N-(6-quinolinyl)acetamide structure](https://static.chemtradehub.com/structs/501/501921-61-5-756a.webp)