Theory of diffusion-influenced reactions in complex geometries
文献情報
Sergey D. Traytak, Francesco Piazza
Chemical transformations involving the diffusion of reactants and subsequent chemical fixation steps are generally termed “diffusion-influenced reactions” (DIR). Virtually all biochemical processes in living media can be counted among them, together with those occurring in an ever-growing number of emerging nano-technologies. The role of the environment's geometry (obstacles, compartmentalization) and distributed reactivity (competitive reactants, traps) is key in modulating the rate constants of DIRs, and is therefore a prime design parameter. Yet, it is a formidable challenge to build a comprehensive theory that is able to describe the environment's “reactive geometry”. Here we show that such a theory can be built by unfolding this many-body problem through addition theorems for special functions. Our method is powerful and general and allows one to study a given DIR reaction occurring in arbitrary “reactive landscapes”, made of multiple spherical boundaries of given size and reactivity. Importantly, ready-to-use analytical formulas can be derived easily in most cases.
おすすめジャーナル

Electroanalysis

Biocatalysis and Biotransformation

Bioorganic & Medicinal Chemistry

Bioorganic & Medicinal Chemistry Letters

Herald of the Russian Academy of Sciences

Heteroatom Chemistry

NDT & E International

Atomization and Sprays

Journal of Chemical Sciences

Critical Reviews in Solid State and Materials Sciences
関連文献
Discovery and characterization of four glycosyltransferases involved in anthraquinone glycoside biosynthesis in Rubia yunnanensis
Shanyong Yi, Tongdong Kuang, Yuanyuan Miao, Yanqing Xu, Zhe Wang, Liao-Bin Dong, Ninghua Tan
DOI: 10.1039/D0QO00579G
Iron catalyzed ketoalkylation and ketoalkylation/etherification of styrenes initiated by selective C–C bond cleavage
Meng-Ting Suo, Shuo Yang, Jun-Cheng Yang, Ze-Yu Liu, Jun-Jie Zhang, Li-Na Guo
DOI: 10.1039/D0QO00671H
Modular synthesis and immunological evaluation of suspected allergenic galactooligosaccharides
Hidde Elferink, Emiel Rossing, Linqiu Cao, Dianne J. Delsing, Andre Groeneveld, Thomas J. Boltje
DOI: 10.1039/C9OB00108E
Asymmetric total synthesis of cryptoconcatone I
Ranjan Kumar Acharyya, Pratik Pal, Shrestha Chatterjee, Samik Nanda
DOI: 10.1039/C9OB00399A
Copper-catalyzed carbonylative synthesis of pyrrolidine-containing amides from γ,δ-unsaturated aromatic oxime esters
Youcan Zhang, Han-Jun Ai
DOI: 10.1039/D0QO00999G
Melanin production by tyrosinase activity on a tyrosine-rich peptide fragment and pH-dependent self-assembly of its lipidated analogue
Jessica A. Hutchinson, Ian W. Hamley, Charlotte J. C. Edwards-Gayle, Valeria Castelletto, Cristian Piras, Rainer Cramer, Radoslaw Kowalczyk, Jani Seitsonen, Janne Ruokolainen, Robert P. Rambo
DOI: 10.1039/C9OB00550A
A cell-permeant small molecule for the super-resolution imaging of the endoplasmic reticulum in live cells
Adiki Raja Sekhar, Bhagaban Mallik, Vimlesh Kumar, Jeyaraman Sankar
DOI: 10.1039/C9OB00408D
Reaction condition controlled nickel(ii)-catalyzed C–C cross-coupling of alcohols
Meng-Juan Zhang, David J. Young, Hai-Yan Li
DOI: 10.1039/C9OB00418A
Diastereoselective construction of the benzannulated spiroketal core of chaetoquadrins enabled by a regiodivergent cascade
Shengxiang Qiu, Hongxin Liu, Haibo Tan
DOI: 10.1039/D0QO00484G
こちらもおすすめ
4'-ブロモビフェニル-3-メトークシーディ.ActionBarはどのように保存すればよいですか?
4'-ブロモビフェニル-3-メトークシーディ.ActionBarは、冷暗所で、直射日光を避け、密栓の容器に保存し、遠隔場所に保管してください。温度は常温(0〜2...
2-異丙基フェニルヒドラジン塩酸塩とは何ですか?
2-異丙基フェニルヒドラジン塩酸塩は、CAS番号58928-82-8を有する化合物で、構造式はC11H14N2HClです。これは塩基性化合物であり、水に溶けやす...
5-(4-クロロフェニル)-4H-1,2,4-三氮唑-3-アミンを取り扱う際の実験室安全事項は何ですか?
5-(4-クロロフェニル)-4H-1,2,4-三氮唑-3-アミンは取り扱いに注意が必要です。PPEとして防塵マスク、ゴーグル、手袋を使用し、ドラフトチャンバーを...
去甲基雷贝拉唑硫醚はどのように合成されますか?
去甲基雷贝拉唑硫醚は、ベンジミダゾール硫化物と3-メチル-4-ピリジノールの反応によって合成されます。具体的には、2-チオキシドベンジミダゾールと3-メチル-4...
2-ブロモ-5-フロロ-N-(2-フェノールメチル)ベンゼンウレアは安全ですか?
2-ブロモ-5-フロロ-N-(2-フェノールメチル)ベンゼンウレアは、毒性や刺激性の実験データに基づき、適切な取扱いと防護措置を講じることで安全に使用できます。...
対甲苯磺酸酯-四聚乙二醇-四氢吡喃醚の物理化学的性質は何ですか?
対甲苯磺酸酯-四聚乙二醇-四氢吡喃醚のCAS番号は86259-89-4です。この化合物は無色の液体で、分子量は約724.8です。高濃度では溶血性が報告されており...
2-(3-(二氟甲基)-4-氟苯基)-4,4,5,5-四甲基-1,3,2-二噁硼戊環はどのように保存すればよいですか?
2-(3-(二氟甲基)-4-氟苯基)-4,4,5,5-四甲基-1,3,2-二噁硼戊環は、室温で暗い場所に保管し、直射日光から遠ざけ、容器は密閉状態で保存してくだ...
6-アミノ-5-クロロ-2-シクロプロピルピリミジンカルボン酸の代替品はありますか?
この化合物の代替品には、ピロリミジン酸やその類似物、またピロリミジンカルボン酸の他の異性体があります。これらの代替品は、特定の化学反応や目的に応じて選択すること...
5-クロロベンゾ[1,3]二オキセイン-4-アミンに適用される法規ガイドラインは何ですか?
5-クロロベンゾ[1,3]二オキセイン-4-アミンはCAS番号379228-45-2に該当します。この化合物はGHS分類でH314(接触により急性毒性がある)と...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

![2-[(E)-(2-Methoxyphenyl)diazenyl]-3-oxo-N-(2-oxo-2,3-dihydro-1H-benzimidazol-5-yl)butanamide structure 2-[(E)-(2-Methoxyphenyl)diazenyl]-3-oxo-N-(2-oxo-2,3-dihydro-1H-benzimidazol-5-yl)butanamide structure](https://static.chemtradehub.com/structs/821/82199-12-0-f1d0.webp)

![Ethyl ({[(2-methyl-2-propanyl)oxy]carbonyl}amino)(2-pyridinyl)acetate structure Ethyl ({[(2-methyl-2-propanyl)oxy]carbonyl}amino)(2-pyridinyl)acetate structure](https://static.chemtradehub.com/structs/313/313490-90-3-dd15.webp)
![Ethyl thieno[3,2-f]quinoline-2-carboxylate structure Ethyl thieno[3,2-f]quinoline-2-carboxylate structure](https://static.chemtradehub.com/structs/299/29948-26-3-f62b.webp)