Iron catalyzed ketoalkylation and ketoalkylation/etherification of styrenes initiated by selective C–C bond cleavage

文献情報

出版日 2020-07-15

DOI 10.1039/D0QO00671H

インパクトファクター 5.281

著者

Meng-Ting Suo, Shuo Yang, Jun-Cheng Yang, Ze-Yu Liu, Jun-Jie Zhang, Li-Na Guo

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要旨

An iron-catalyzed ketoalkyl-Heck-type coupling initiated by radical C–C bond cleavage is described. The features of this protocol include mild conditions (40 °C, free of ligands and bases), broad substrate scope, excellent functional group tolerance and stereoselectivity. Satisfactorily, this Fe-based catalytic system was also applicable for the three-component ketoalkylation/etherification of styrenes.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Iron catalyzed ketoalkylation and ketoalkylation/etherification of styrenes initiated by selective C–C bond cleavage

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