Direct borylation of benzyl alcohol and its analogues in the absence of bases

文献情報

出版日 2015-09-10

DOI 10.1039/C5QO00243E

インパクトファクター 5.281

著者

Zhi-Chao Cao, Fei-Xian Luo, Wen-Juan Shi

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要旨

Direct borylation of arylmethanols to synthesize important and useful benzylboronates was carried out through Pd(OAc)2-catalyzed sp3 C–O activation. This borylation is compatible with various functional groups under mild conditions in the absence of any bases, offering an atom- and step-economical way to produce benzylboron compounds.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Direct borylation of benzyl alcohol and its analogues in the absence of bases

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