Phonon-assisted energy back transfer-induced multicolor upconversion emission of Gd2O3:Yb3+/Er3+ nanoparticles under near-infrared excitation
文献情報
Jun Liu, Huawei Deng, Zhanyun Huang, Yueli Zhang, Dihu Chen, Yuanzhi Shao
Manipulation of upconversion (UC) emission is of particular importance for multiplexed bioimaging. Here, we precisely manipulate the UC color output by utilizing the phonon-assisted energy back transfer (EBT) process in ultra-small (sub-10 nm) Gd2O3:Yb3+/Er3+ UC nanoparticles (UCNPs). We synthesized the Gd2O3:Yb3+/Er3+ UCNPs by adopting the laser ablation in liquid (LAL) technique. The synthesized Gd2O3:Yb3+/Er3+ UCNPs are small spherical and monoclinic structures. Continuous color-tunable (from green to red) UC fluorescence emission is achieved by increasing the concentration of Yb3+ ions from 0 to 15 mol%. A phonon-assisted energy back transfer (EBT) process from Er3+ (4S3/2 → 4I13/2) to nearby Yb3+ (2F7/2 → 2F5/2), which can significantly enhance red emission at 672 nm and decrease green emission, is responsible for the color-tunable UC emission by increasing the Yb3+ concentration in Gd2O3:Yb3+/Er3+ UC nanoparticles.
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