Catalytic Y-tailed amphiphilic homopolymers – aqueous nanoreactors for high activity, low loading SCS pincer catalysts

文献情報

出版日 2013-01-28

DOI 10.1039/C3PY21137A

インパクトファクター 5.582

著者

Joseph P. Patterson, Pepa Cotanda, Elizabeth G. Kelley, Adam O. Moughton, Annhelen Lu, Thomas H. Epps, III, Rachel K. O'Reilly

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要旨

A new amphiphilic homopolymer bearing an SCS pincer palladium complex has been synthesized by reversible addition fragmentation chain transfer polymerization. The amphiphile has been shown to form spherical and worm-like micelles in water by cryogenic transmission electron microscopy and small angle neutron scattering. Segregation of reactive components within the palladium containing core results in increased catalytic activity of the pincer compound compared to small molecule analogues. This allows carbon–carbon bond forming reactions to be performed in water with reduced catalyst loadings and enhanced activity.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Catalytic Y-tailed amphiphilic homopolymers – aqueous nanoreactors for high activity, low loading SCS pincer catalysts

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