The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates

文献情報

出版日 2013-03-04

DOI 10.1039/C3PY00270E

インパクトファクター 5.582

著者

Athina Anastasaki, Christopher Waldron, Paul Wilson, Ronan McHale, David M. Haddleton

原文を見る

要旨

Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me6Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.

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掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates

文献情報

おすすめジャーナル

関連文献

Isolation and structural characterization of an optically active intermediate in the oxidative addition of methyl iodide on a rhodium(i) centre

Novel fullerene–porphyrin–fullerene triad linked by metal axial coordination: Synthesis, X-ray crystal structure, and spectroscopic characterizations of trans-bis([60]fullerenoacetato)tin(iv) porphyrin

Self-oriented pseudoisocyanine J-aggregates in solution

Highlights from the 39th ESF/EUCHEM Conference on Stereochemistry, Bürgenstock, Switzerland, April 2004

Bundles of identical double-walled carbon nanotubes

Assembly of large simple 1D and rare polycatenated 3D molecular ladders from T-shaped building blocks containing a new, long N,N′-bidentate ligand

Mono- and bis(tetrathiafulvaleno)hexadehydro[12]annulenes

Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(μ-Bu)(μ-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

New reactions in water: metal-free conversion of alcohols and ketones into α-iodoketones

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Polymer Chemistry

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