Pillar[5]arene–neutral guest recognition based supramolecular alternating copolymer containing [c2]daisy chain and bis-pillar[5]arene units

文献情報

出版日 2013-05-01

DOI 10.1039/C3PY00462G

インパクトファクター 5.582

著者

Xiaoyang Wang, Kang Han, Jian Li, Xueshun Jia

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要旨

A novel supramolecular alternating copolymer with [c2]daisy-chain dimer and macrocycle host dimer as repeating units has been fabricated. A key factor for this new assembly strategy is based on a [c2]daisy-chain pseudorotaxane bearing additional unbound recognition sites at both ends, which was successfully achieved from a careful designed heterotritopic (AB2-type) copillar[5]arene. By utilizing the intermolecular host–guest interactions between the double-threaded dimer and a pillar[5]arene dimer, a linear supramolecular polymer was prepared. These results provided not only a convenient approach for the construction of [c2]daisy chain based supramolecular polymers, but also a novel method for building supramolecular alternating copolymers.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Pillar[5]arene–neutral guest recognition based supramolecular alternating copolymer containing [c2]daisy chain and bis-pillar[5]arene units

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Polymer Chemistry

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