Recent developments in the study of ionic liquid interfaces using X-ray photoelectron spectroscopy and potential future directions
文献情報
Hans-Peter Steinrück
A perspective is given on the potential of X-ray photoelectron spectroscopy to investigate ionic liquid (IL) interfaces and related bulk properties. To allow for cross-correlation of different IL properties, the study is restricted to imidazolium-based systems. By systematic variation of alkyl chain lengths, by investigation of different anions, and by introduction of functional groups detailed information on surface orientation, enrichment effects, cation–anion interactions, and the correlation to macroscopic properties such as density and surface tension of ILs are derived. Furthermore, the molecular arrangement and growth behaviour of ultrathin ionic liquid layers on various substrates, in situ monitoring of chemical reactions, and the dissolution of transition metal complexes are addressed.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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