Tribenzotriquinacene-based polymers of intrinsic microporosity

文献情報

出版日 2011-08-11

DOI 10.1039/C1PY00294E

インパクトファクター 5.582

著者

James Vile, Mariolino Carta, C. Grazia Bezzu, Neil B. McKeown

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要旨

Bowl-shaped tribenzotriquinacene (TBTQ) derivatives containing hydroxyl groups at their peripheral sites are successful monomers for the synthesis of polymers of intrinsic microporosity (PIMs) with examples of both network and non-network PIMs demonstrated. Nitrogen adsorption measurements reveal apparent surface areas in the range of 560–670 m2 g−1 for the TBTQ-PIMs. A network structure and i-propyl, rather than methyl substitution at the apical site of the TBTQ unit, appear to favour porosity.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Tribenzotriquinacene-based polymers of intrinsic microporosity

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