Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like Mg3(2,5-fur-di-yl)3 substructure

文献情報

出版日 2008-09-19

DOI 10.1039/B812147H

インパクトファクター 6.222

著者

Victoria L. Blair, Alan R. Kennedy, Jan Klett, Robert E. Mulvey

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要旨

Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium–hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like Mg3(2,5-fur-di-yl)3 substructure

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