Enhanced reactivity of hydrophobic vitamin B12 towards the dechlorination of DDT in ionic liquid

文献情報

出版日 2007-03-23

DOI 10.1039/B700725F

インパクトファクター 6.222

著者

Md. Abdul Jabbar, Hisashi Shimakoshi, Yoshio Hisaeda

原文を見る

要旨

The electrolytic reductive dechlorination of 1,1-bis(p-chlorophenyl)-2,2,2-trichloroethane (DDT) in the ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) in the presence of a cobalamin derivative afforded 1,1′-(ethylidene)bis(4-chlorobenzene) (DDO) and 1,1′-(ethenylidene)bis(4-chlorobenzene) (DDNU) with 1,1′-(2-chloroethylidene)bis(4-chlorobenzene) (DDMS); the enhanced reactivity, as well as the recyclability of the cobalamin derivative catalyst in IL, makes the present system more efficient for the development of “green” technologies.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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