Synthesis of propargylic fluorides from allenylsilanes
文献情報
Laurence Carroll, Mª Carmen Pacheco, Ludivine Garcia, Véronique Gouverneur
Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.
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