From particles to stabilizing blocks – polymerized ionic liquids in aqueous heterophase polymerization

文献情報

出版日 2014-05-16

DOI 10.1039/C4PY00458B

インパクトファクター 5.582

著者

Ran Yu, Klaus Tauer

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要旨

Suspensions of polyvinylimidazolium salts with long alkyl chains (polymerized ionic liquids) are a new class of reactive electrostatic stabilizers for aqueous polymer dispersions with dual functions – as a reductant in a redox initiator system and as a colloidal stabilizer. Studying the properties of di- and triblock copolymer dispersions (with N-isopropyl acryl amide and/or hydrophobic monomers) made with these reactive suspensions reveals an interesting behavior which is described as the principle of relative hydrophilicity. Following this principle, the colloid chemical behavior of the polyvinylimidazolium salt block depends on the relative hydrophilicity in comparison with the other blocks.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

From particles to stabilizing blocks – polymerized ionic liquids in aqueous heterophase polymerization

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