A chiral porous 3D metal–organic framework with an unprecedented 4-connected network topology
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Chuan-De Wu, Wenbin Lin
A novel homochiral 3D metal–organic framework [CdL2(H2O)2][ClO4]2·2DMF·3EtOH·5/3H2O, 1, (L = (R)-6,6′-dichloro-2,2′-diethoxy-1,1′-binaphthyl-4,4′-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies.
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