A quasi-covalent metal–metal bond in an early–late heterobimetallic Ti–Pt complex stabilized by phosphinoenolate ligands‡

文献情報

出版日 2003-02-03

DOI 10.1039/B211289M

インパクトファクター 6.222

著者

Pierre Braunstein, Xavier Morise, Marc Bénard, Marie-Madeleine Rohmer, Richard Welter

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要旨

An unusual early–late bimetallic complex with direct metal–metal bonding is obtained from a phosphinoenolate ligand-assisted reaction between Ti(IV) and Pt(0) reagents which occurs by formal insertion of the Pt(0) centre into a Ti(IV)–O bond; X-ray data and EHMO calculations indicate the presence of a quasi-covalent Ti(III)–Pt(I) bond (2.721(2) Å).

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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A quasi-covalent metal–metal bond in an early–late heterobimetallic Ti–Pt complex stabilized by phosphinoenolate ligands‡

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