Rational design of a carbon/potassium poly(heptazine imide) heterojunction for enhanced photocatalytic H2 and H2O2 evolution

文献情報

出版日 2023-11-27

DOI 10.1039/D3TA05701A

インパクトファクター 12.732

著者

Christian Mark Pelicano, Jiaxin Li, María Cabrero-Antonino, Ingrid F. Silva, Lu Peng, Nadezda V. Tarakina, Sergio Navalón, Hermenegildo García, Markus Antonietti

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要旨

We present the rational design of carbon/potassium poly(heptazine imide) (KPHI) heterostructures via one-step salt-melt assisted condensation for efficient photocatalysis. Hybridizing KPHI with an adenine-derived carbonaceous material (Ad-carbon) displayed an outstanding photocatalytic H2 evolution activity (738 μmol h−1 gcat−1; with 3 wt% Pt as the cocatalyst) and photocatalytic H2O2 production (3.94 mmol h−1 gcat−1). We establish that the Ad-carbon simultaneously operates as an electron acceptor and a photosensitizer based on structural, optical and photo(electro)chemical characterization. Building an intimate heterojunction between the Ad-carbon and KPHI induced spatial charge separation and prolonged the carrier lifetime. From electrocatalysis, we confirmed that coupling Ad-carbon with KPHI enhanced the surface reaction kinetics towards H2 evolution and O2 reduction reactions. Moreover, visual evidence of superior charge transport in the hybrid photocatalyst is revealed through the photodeposition of smaller Pt nanoparticles (∼7 nm) with uniform distribution on the carbon regions, which also accounts for the increased catalytic activity.

掲載誌

Journal of Materials Chemistry A

CiteScore: 19.5

自己引用率: 4.7%

年間論文数: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

Rational design of a carbon/potassium poly(heptazine imide) heterojunction for enhanced photocatalytic H2 and H2O2 evolution

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掲載誌

Journal of Materials Chemistry A

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