A single-phase gadolinium-doped ceria cathode for highly efficient CO2 electrolysis

文献情報

出版日 2023-11-03

DOI 10.1039/D3TA03977C

インパクトファクター 12.732

著者

Ahmad Shaur, Michel Drazkowski, Shaochen Zhu, Bernard Boukamp

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要旨

High-temperature solid-oxide CO2 electrolysers enable high-efficiency conversion of electrical energy to valuable fuels and chemicals and as such facilitate a sustainable-energy technology. Conventional cermet-based fuel electrodes used in such solid-oxide cells (SOCs) like nickel–yttria-stabilized zirconia (Ni–YSZ) suffer from morphological degradation and destructive carbon deposition. In recent years, there has been an increasing interest in employing single-phase ceria-based fuel electrodes, which are known to exhibit excellent carbon deposition resistance. Under sufficiently reducing conditions, doped ceria (substituted with trivalent cations such as samarium or gadolinium to generate mobile oxygen vacancies) becomes a mixed ionic–electronic conductor, showing appreciable electronic conductivity. Here, we show for the first time stable high performance in CO2 electrolysis using a ceria-based SOC. The single full cell incorporating a 10 mol% gadolinium-doped ceria (GCO) fuel electrode delivers a current density as high as 1.51 A cm−2 at 800 °C during pure CO2 electrolysis, which is the best electrode performance reported to date among all-ceramic cathode materials. We demonstrate that the electrode performance in CO2 electrolysis is linked with the electronic conductivity, and hence, with the electronic charge carrier concentration in GCO. The results of the present work pave the way for development of robust, nickel-free SOCs for direct CO2 electrolysis.

掲載誌

Journal of Materials Chemistry A

CiteScore: 19.5

自己引用率: 4.7%

年間論文数: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

A single-phase gadolinium-doped ceria cathode for highly efficient CO2 electrolysis

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