Electrochemical (radio)-halodesilylation of aromatic silanes

文献情報

出版日 2023-11-24

DOI 10.1039/D3QO01553J

インパクトファクター 5.281

著者

Kehao Gong, Long Lin, Xinyan Gao, Xiaojun Zeng, Bo Xu, Junbin Han

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要旨

We have developed a green and efficient electrochemical halodesilylation of trimethylsilanes to synthesize aryl halides. The reaction was carried out under mild conditions without sophisticated equipment, transition metal catalysts, hazardous oxidants, and additional electrolytes. The protocol also has broad substrate scope and high functional group tolerance. Moreover, this electrochemical method is applicable to radioactive iodine labeling.

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Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Electrochemical (radio)-halodesilylation of aromatic silanes

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