Photoredox chromium and cobalt dual catalysis for carbonyl allylation with butadiene via allyl radical intermediates

文献情報

出版日 2023-12-18

DOI 10.1039/D3QO01403G

インパクトファクター 5.281

著者

Huaipu Yan, Dandan Zhang, Yonghong Liu, Xin Wang, Zhixian Wu, Yunhe Jin, Xiaobo Ding, Jing-Ran Shan, Erjun Hao

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要旨

Here, we report an allylation reaction of aldehydes with butadiene using cobalt and chromium catalysts via a metal-hydride hydrogen atom transfer (MHAT) pathway under visible light irradiation. A variety of homoallylic alcohols can be obtained with high yield and excellent diastereoselectivity. The cheap and readily available raw materials and catalysts make the reaction system have a great potential application value.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Photoredox chromium and cobalt dual catalysis for carbonyl allylation with butadiene via allyl radical intermediates

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